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Öğe Assessment of the usability conditions of Sb2O3-PbO-B2O3 glasses for shielding purposes in some medical radioisotope and a wide gamma-ray energy spectrum(DE GRUYTER POLAND SP Z O O, 2022) Almisned, Ghada; Şen Baykal, Duygu; Kılıç, Gökhan; Susoy, Gülfem; Zakaly, Hesham M. H.; Ene, Antoaneta; Tekin, Hüseyin OzanWe report some fundamental gamma-ray shielding properties and individual transmission factors (TFs) of five distinct glass samples with a nominal composition of xSb(2)O(3)center dot (40 - x)PbO center dot 60B(2)O(3)center dot 0.5CuO and (where; 0 <= x <= 40 mol%). Phy-X/PSD and MCNPX (version 2.7.0) Monte Carlo code are utilized to determine several critical parameters, such as cross-sections, attenuation coefficients, half and tenth value layers, build-up factors, and TFs. A general transmission setup is designed using basic requirements. Accordingly, TFs are evaluated for several medical radioisotopes. Next, the gamma-ray shielding parameters and TFs are assessed together in terms of providing the validity of the findings. Our results showed that there is a positive contribution of increasing Sb2O3 amount in the glass matrix owing its direct effect to the density increment as well. This positive effect on gamma-ray shielding properties is also observed for decreasing mean free path values from S1 to S5 samples. The exposure build-up factor (EBF) and energy absorption build-up factor (EABF) values, increasing the quantity of Sb2O3 supplementation, resulted in a general reduction in EBF and EABF values (i.e., from 0.5 to 40 mfp). When the quantity of Sb2O3 rises from S1 to S5, the collision rate of incoming gamma rays in glass samples increases significantly. The TF figures reveal that S5 showed the least transmission behavior across all the above-mentioned studied glass thicknesses. It can be concluded that increasing the Sb2O3 additive is a beneficial and monotonic technique, when the gamma-ray shielding qualities or TF values must be further enhanced.Öğe Bismuth(III) oxide and boron(III) oxide substitution in bismuth-boro-zinc glasses: a focusing in nuclear radiation shielding properties(ELSEVIER GMBH, 2023) Almisned, Ghada; Bilal, Ghaida; Şen Baykal, Duygu; Ali, Fatema T.; Kılıç, G.; Tekin, Hüseyin OzanDoping the glass structure with Bi2O3 `is known to increase structural stability, and to drastically alter physical parameters including density and molar volume. The goal of this work was to assess the nuclear radiation attenuation competences of several types of glasses based on the xBi2O3-(70x)B2O3-8BaO-16ZnO-5.5SiO2- 0.5Sb2O3 system. In order to determine the requisite gamma shielding parameters, as well as effective conductivity at 300 K and buildup factors, five different glasses with varied Bi2O3 concentration (i.e., from 10 mol.% to 30 mol.%) were examined thoroughly. These critical parameters were determined using the Phy-X/PSD program. In addition, factors such as half value layer (HVL), tenth value layer (TVL), and mean free path (mfp) were examined over a wide energy range of 0.015-15 MeV. The findings revealed that the amount of Bi2O3 reinforced in each sample is critical in determining the samples' shielding abilities. The linear attenuation coefficients (mu) and mass attenuation coefficient (mu m) values were reported in the highest level for the sample with the highest Bi2O3 content. For glass sample A5, the lowest mean free path, half value layer, and tenth value layer values were also reported. The effective conductivity and effective atomic number had an inverse relationship with photon energy, meaning that as energy increased, the effective conductivity and effective atomic number declined fast, especially in low-energy regions. The greatest values for both parameters were found in glass sample A5. Furthermore, the exposure buildup factor and energy absorption buildup factor values for glass sample A5 were the lowest. A5 glass sample with the chemical composition 30Bi2O3-(70 30) B2O3-8BaO-16ZnO-5.5SiO2- 0.5Sb2O3 and a density of 5.8391 g/ cm3 was found to have exceptional gamma-ray attenuation qualities, according to our findings. It can be concluded that the prospective attributes of Bi2O3-doped glass systems and associated glass compositions would be beneficial for scientific community in terms of providing a clearer view for some advanced applications of these glass types.Öğe A critical evaluation on nuclear safety properties of novel cadmium oxide-rich glass containers for transportation and waste management: benchmarking with a reinforced concrete container(FRONTIERS MEDIA SA, 2022) Almisned, Ghada; Şen Baykal, Duygu; Kılıç, Gökhan; İlik, Erkan; Zakaly, Hesham M. H.; Ene, Antoaneta; Tekin, Hüseyin OzanWe examine the nuclear safety properties of a newly designed cadmiumoxide-rich glass container for nuclear material to a bitumen-reinforced concrete container. Individual transmission factors, detectormodelling, and energy deposition (MeV/g) in the air are calculated using MCNPX (version 2.7.0) general purpose Monte Carlo code. Two container configurations are designed with the material properties of cadmium dioxide-rich glass and Concrete + Bitument in consideration. First, individual transmission factors for 60Co and 137Cs radioisotopes are calculated. To evaluate potential environmental consequences, energy deposition amounts in the air for 60Co and 137Cs are also determined. The minimum gamma-ray transmission rates for two container types are reported for a cadmium dioxiderich glass container. In addition, the quantity of energy deposition is varied depending on the container type, with a lower value for cadmium dioxide-rich glass container. The 40% cadmium dioxide-doped glass container provides more effective safety than the Cement + Bitumen container, according to the overall findings. In conclusion, the utilization of cadmium dioxide-doped glass material along with its high transparency and advanced material properties may be a significant and effective option in areas where concrete is required to assure the safety of nuclear materials.Öğe Mechanical properties, elastic moduli, transmission factors, and gamma-ray-shielding performances of Bi2O3-P2O5-B2O3-V2O5 quaternary glass system(DE GRUYTER POLAND, 2022) Tekin, Hüseyin Ozan; ALMisned, Ghada; Rammah, Yasser Saad; Susoy, Gulfem; Ali, Fatema T.; Şen Baykal, Duygu; Zakaly, Hesham M. H.; Issa, Shams A. M.; Ene, AntoanetaMechanical properties, elastic moduli, transmission factors (TFs), and gamma-ray shielding performance of quaternary glass systems with chemical composition (0.25-x)Bi2O3-xB(2)O(3)-0.75(50%P2O5-50%V2O5), where x = 0.05 (S1), 0.10 (S2), 0.15 (S3), and 0.20 (S4) mol%, were comprehensively studied. The MCNPX code, Phy-X/PSD software, and the Makishima-Mackenzie model were utilized to achieve the mentioned purposes. The values of the packing density (V (t)) decreased from 0.634432 to 0.600611, while those of the dissociation energy (G (t)) increased from 51.6125 kJ/cm(3) for the S1 glass sample (with Bi2O3 = 5 mol%) to 56.7525 kJ/cm(3) for the S4 glass sample (with Bi2O3 = 20 mol%). This means that the mechanical properties were enhanced by increasing the Bi2O3 content in glasses. Linear (mu) and mass attenuation (mu (m)) coefficients for the S4 glass sample were the greatest compared to those for glass materials investigated, i.e., (mu, mu (m))(S1) < (mu, mu (m))(S2) < (mu, mu (m))(S3) < (mu, mu (m))(S4). Half- and tenth-value layers (HVL and TVL, respectively) follow the trend: (HVL, TVL)(S1) > (HVL, TVL)(S2) > (HVL, TVL)(S3) > (HVL, TVL)(S4). The effective atomic number (Z (eff)) of investigated glasses has the same trend as of linear and mass attenuation coefficients. Our findings indicate that increasing the amount of Bi2O3 reinforcement decreased the exposure buildup factor and energy absorption buildup factor values for all mean free path values (0.5-40 mfp). All glasses recorded the minimum TF values at a thickness of 3 cm. The findings would benefit the scientific community in determining the most appropriate additive bismuth(iii) oxide/diboron trioxide type and related glass composition to provide the shielding properties previously mentioned in terms of needs and utilization requirements, as well as the most suitable glass composition.Öğe Mechanical properties, elastic moduli, transmission factors, and gamma-ray-shielding performances of Bi2O3-P2O5-B2O3-V2O5 quaternary glass system (vol 20, pg 314, 2022)(DE GRUYTER POLAND SP Z O O, 2022) Tekin, Hüseyin Ozan; Almisned, Ghada; Rammah, Yasser Saad; Susoy, Gülfem; Ali, Fatema T.; Şen Baykal, Duygu; Zakaly, Hesham M. H.; Issa, Shams A. M.; Ene, AntoanetaNo Abstract Available.
