Synthesis and characterization of Nb 5+and Sm 3+-doped 13-93 bioactive glass particles with improved photon transmission properties for advanced biomedical and dental applications
Küçük Resim Yok
Tarih
2024
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Bioactive glasses are renowned for their applications in dentistry, serving as restorative materials, dental adhesives, intracanal medicaments, and agents for enamel remineralization. Niobium pentoxide (Nb 2 O 5 ) is employed in dental adhesive resins and orthodontic adhesives, offering radio -pacifying properties essential for dental materials. Samarium oxide (Sm 2 O 3 ) emerges as a potential additive in aesthetic restorative dental ceramics and resins, enhancing the natural fluorescence of teeth. In this study Nb 2 O 5 and Sm 2 O 3 -doped (1, 3, and 5 wt%) 13 -93 bioactive glass particles were synthesized via the sol-gel method, tailored for dental implementations. We conducted a comprehensive analysis of the physical, structural, and optical properties of the resultant glass powders. Additionally, their in vitro bioactivity and ionizing radiation shielding characteristics were rigorously evaluated. The results indicate that Sm 3 + ions preserve the amorphous nature of the silicate glasses, while Nb 5 + incorporation leads to the crystallization of the T-Nb 2 O 5 phase. Bioactivity assays across three physiological fluids -simulated body fluid, alpha-minimum essential medium, and phosphate -buffered saline, demonstrated the ability of doped glasses to facilitate hydroxyapatite layer formation, with the most pronounced bioactivity observed in phosphate -buffered saline immersed samples. Furthermore, radiation shielding simulations reveal that the addition of Nb 2 O 5 and Sm 2 O 3 enhances the ionizing radiation attenuation capabilities of the glasses, a property that holds significant promise for protecting against radiation in dental radiology. It can be concluded that the dual functionality of Nb 5 + and Sm 3 + -doped bioactive glasses, which may revolutionize restorative dental practices and offer improved protection in radiological applications.
Açıklama
Anahtar Kelimeler
Bioactive Glass, Sol-Gel, Samarium, Niobium, Dentistry, Biomedical Applications
Kaynak
Ceramics international
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
50
Sayı
17
Künye
Deliormanlı, A. M., ALMisned, G., & Tekin, H. O. (2024). Synthesis and characterization of Nb5+ and Sm3+-doped 13-93 Bioactive Glass Particles with Improved Photon Transmission Properties for Advanced Biomedical and Dental Applications. Ceramics International.