Impact of incremental zinc-oxide incorporation on optical, magnetic, mechanical and photon transmission properties of K2O, SrF2, PbO containing borate-glasses

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Tarih

2024

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

This study examines the radiation shielding properties of borate glass systems, with a focus on the simultaneous enhancement of optical, mechanical, and magnetic characteristics. The glass composition is represented by formula (55-x)B2O3+25PbO+10SrF2+10K2O 2 O 3 +25PbO +10SrF 2 +10K 2 O + xZnO (where x: 0.0-10.0 mol%). By manipulating the ZnO concentration, we aimed to investigate its role as a radiation attenuator and its effects on the glass's optical, mechanical, and magnetic properties. Using traditional melt-quenching techniques, we produced the glass samples and examined their density, molar volume, linear attenuation coefficients (GLAC), LAC ), mean free paths (GMFP), MFP ), half-value layers (GHVL), HVL ), and optical and magnetic properties. Our findings demonstrate that higher ZnO concentrations lead to a significant increase in density and a corresponding decrease in molar volume, thereby enhancing the glasses' ability to shield against gamma radiation. The radiation attenuation analysis revealed that increasing ZnO content substantially improves G LAC values across the energy range of 356-1333 keV. Additionally, ZnO incorporation decreases the optical bandgap, shifting the UV absorption edge to shorter wavelengths and enhancing UV dielectric capacity. Magnetic properties were assessed using vibrating sample magnetometer (VSM) measurements, showing a strong correlation between ZnO content and the effective atomic number (Zeff). eff ). It can be concluded that ZnO not only contributes to radiation shielding but also modifies the electronic structure of the glass, impacting its optical absorption properties.

Açıklama

Anahtar Kelimeler

Radiation Shielding, Borate Glasses, Optical Properties, Magnetic, Gamma Ray Attenuation, UV Absorption Edge

Kaynak

Optical materials

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

154

Sayı

Künye

Almousa, N., Issa, S. A., Zakaly, H. M., Abulyazied, D. E., Abouhaswa, A. S., & Tekin, H. O. (2024). Impact of incremental zinc-oxide incorporation on optical, magnetic, mechanical and photon transmission properties of K2O, SrF2, PbO containing borate-glasses. Optical Materials, 154, 115770.