Atakol, ArdaZeydanli, DamlaGöver, TuğçeAtakol, MelikeSerbest, HakanKarakebap, KübraBüyük, Muhammed AliAtakol, OrhanBakirdere, Sezgin2025-04-172025-04-172025Atakol, A., Zeydanli, D., Göver, T., Atakol, M., Serbest, H., Karakebap, K., ... & Bakirdere, S. (2025). Trace determination of cobalt in heather leaf tea by matrix matching calibration assisted flame atomic absorption spectrometry following a dispersive liquid–liquid microextraction utilizing a Schiff base ligand. Measurement, 116879.0263-22411873-412Xhttp://dx.doi.org/10.1016/j.measurement.2025.116879https://hdl.handle.net/20.500.12713/6184In this study, an analytical method that involves dispersive liquid-liquid microextraction for extraction and enrichment of Co was developed for its determination in heather leaf tea infusions. N,N'-bis(2-hydroxyacetophenylidene)-1,3-propanediamine was utilized to form the complex extracted in chloroform with methanol as a dispersive solvent. The experimental parameters were optimized to allow for an enhancement of detection power by 35.6-folds compared to direct FAAS measurements while lowering the limit of detection to 0.0154 mg/L and the limit of quantification to 0.0513 mg/L and providing a linear range of 0.050-0.75 mg/L. Spiked recovery experiments were conducted on two brands of heather leaf tea where a matrix matching strategy was employed for further reduction of interferences. The recovery results obtained in the range of 78.7-128.4 % supported the accuracy of the proposed method that promises an economical and easy-to-apply process for the trace determination of cobalt in herbal tea matrices.eninfo:eu-repo/semantics/closedAccessCobaltDispersive Liquid–Liquid MicroextractionFlame Atomic Absorption SpectrometryHeather LeafArticle24817WOS:0014231545000012-s2.0-85216888857Q110.1016/j.measurement.2025.116879Q1