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Öğe Dysprosium-enriched polymer nanocomposites: Assessing radiation shielding and optical properties(Elsevier, 2024) Abulyazied, D. E.; Issa, Shams A. M.; Saudi, H. A.; Abomostafa, H. M.; Zakaly, Hesham M. H.This paper includes a comprehensive analysis of the radiation shielding, optical properties, and structural makeup of polymer composites that contain Dy2O3 additions. XRD-pattern investigates the effect of loading Dy2O3 content on PS, with the average crystallite size of Dy2O3 decreases from 39 nm to 30 nm as Dy2O3 increases from 2.5 to 7.5 wt% in the PS matrix. The optical properties of the nanocomposites showed that with the increase in the Dy2O3 content, the transmittance, as well as the direct and indirect band gap, decreased. The EIndirect bandgap decreased from 3.1 to 2.75 eV with a Dy2O3 increase from 0 to 7.5 wt%, while the Edirect g g Bandgap reduced from 4.6 to 4.35 eV. While the Urbach energy Eu and the refractive index increase, Eu rises from 0.48 to 0.60 e V, and n improves from 1.4 to 1.78 from 0 to 7.5 wt%. In order to conduct an accurate analysis of the gamma-ray attenuation capabilities of the selected new polymer composites, these composites were manufactured with varying proportions of the additive components. With the assistance of a Na(Tl) detector, experimental assessments were carried out on the gamma rays throughout a broad spectrum of photon energies, ranging from 81 keV up to 1416 keV. The sample encased in PS/Dy7.5 demonstrates excellent radiation attenuation, and it is important to note that this novel polymer shielding material does not include any hazardous components.Öğe Effects of WO3 reinforcement on the properties of poly(lactic acid) composites for radiation shielding(Pergamon-Elsevier Science Ltd, 2023) Issa, Shams A. M.; Alrowaily, Albandari W.; Abulyazied, D. E.; Ali, E. S.; Zakaly, Hesham M. H.During this work, efforts have been made to improve the gamma radiation shielding capabilities of poly(lactic acid) (PLA) by including tungsten trioxide (WO3). Simulations and theoretical analyses have been performed on the parameters of radiation shielding. They have been tested across a broad spectrum of energies, from 0.015 to 15 MeV. The values suggest that naturally occurring composites with a high WO3 content may be utilized to improve the gamma shielding properties of PLA/TO (TO & EQUIV;tungsten trioxide) composites for protection applications; such composites can be employed as a covering for the solar cells to prevent damage. The composite samples made of PLA and WO3 were analyzed for a range of photon energies. The results showed rise of considerable proportions in the values of linear attenuation coefficient (& mu;) and mass attenuation coefficient & mu;m at 0.08 MeV, due to the k-absorption edge of tungsten. In addition, & mu; and & mu;m for all samples at selected photon energy are increase as the WO3 content increases and decreases with increasing photon energy. The half value layer (T0.5) decreased as the WO3 content increased, with the highest values seen at 15 MeV and the lowest values at 15 keV. The behavior of the mean free path (& lambda;) was identical to T0.5 with regards to the amount of WO3 and the energy of the photon. The T0.5 values of the PLA-W7 were lower than other polymer materials, making it a more efficient material for filtering radiation. The Zeff values of the PLA/TO composite samples were the highest at 0.08 MeV and showed a trend of increasing with energy to 15 MeV. The exposure buildup factor (EBF) and energy absorption buildup factor EABF values were computed using the G-P fitting method and showed that the lowest values were presented for the PLA-W7. An increase in WO3 reinforcement in the PLA sample contributed to the decreased EBF-EABF values. The shielding parameters were determined through calculations done using both Phy-X/PSD and FLUKA, and the results from both are in good agreement with each other. The results of the study demonstrate the effectiveness of PLA-W7 as a material for radiation shielding.Öğe Impact of incremental zinc-oxide incorporation on optical, magnetic, mechanical and photon transmission properties of K2O, SrF2, PbO containing borate-glasses(Elsevier, 2024) Almousa, Nouf; Issa, Shams A. M.; Zakaly, Hesham M. H.; Abulyazied, D. E.; Abouhaswa, A. S.; Tekin, Hüseyin OzanThis study examines the radiation shielding properties of borate glass systems, with a focus on the simultaneous enhancement of optical, mechanical, and magnetic characteristics. The glass composition is represented by formula (55-x)B2O3+25PbO+10SrF2+10K2O 2 O 3 +25PbO +10SrF 2 +10K 2 O + xZnO (where x: 0.0-10.0 mol%). By manipulating the ZnO concentration, we aimed to investigate its role as a radiation attenuator and its effects on the glass's optical, mechanical, and magnetic properties. Using traditional melt-quenching techniques, we produced the glass samples and examined their density, molar volume, linear attenuation coefficients (GLAC), LAC ), mean free paths (GMFP), MFP ), half-value layers (GHVL), HVL ), and optical and magnetic properties. Our findings demonstrate that higher ZnO concentrations lead to a significant increase in density and a corresponding decrease in molar volume, thereby enhancing the glasses' ability to shield against gamma radiation. The radiation attenuation analysis revealed that increasing ZnO content substantially improves G LAC values across the energy range of 356-1333 keV. Additionally, ZnO incorporation decreases the optical bandgap, shifting the UV absorption edge to shorter wavelengths and enhancing UV dielectric capacity. Magnetic properties were assessed using vibrating sample magnetometer (VSM) measurements, showing a strong correlation between ZnO content and the effective atomic number (Zeff). eff ). It can be concluded that ZnO not only contributes to radiation shielding but also modifies the electronic structure of the glass, impacting its optical absorption properties.Öğe Improving electrical, optical and radiation shielding properties of polyvinyl alcohol yttrium oxide composites(Elsevier, 2023) Issa, Shams A. M.; Abulyazied, D. E.; Alrowaily, Albandari W.; Saudi, H. A.; Ali, E. S.; Henaish, A. M. A.; Zakaly, Hesham M. H.This research aims to study the impact of yttrium oxide on the radiation protection features of polyvinyl alcohol (PVA) for gamma shielding applications. The yttrium oxide (Y2O3) was instilled through the PVA matrix by different contents (x 1/4 0.1 wt%, 0.3 wt%, 0.7 wt%, 0.9 wt%). The morphology of the prepared PVA/Y2O3 composites was characterized using scanning electron microscopy (SEM). The samples were investigated using absorption edge, transmittance spectra and dielectric properties. The transmittance and the bandgap energy decrease as the Y2O3 content increases while there is an increase in epsilon 0 and epsilon 00 as well as the ac conductivity with the content increment of Y2O3 till 0.7 wt%. The temperature dependence of the dc conductivity was measured for all samples in the range of 260-460 K, and it increases with the temperature increasing. To correlate the electrical characteristics of the PVA/Y2O3 composites with their structure and evaluate electrical properties with the help of equivalent circuit matching with the experimentally electrical response in the impedance spectrum, the radiation protection properties were also investigated to get the radiation shielding performance of these PVA/Y2O3 composite films with varying Y2O3 content. The linear attenuation coefficient (m), half value layer (T0.5), and mass attenuation coefficient (mm) were measured. According to all obtained data, PVA/Y2O3 composite films with various percentages (0.1 wt%, 0.3 wt%, 0.7 wt%, 0.9 wt%) can be used as a radiation shielding material.(c) 2023 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.
