EFFECTS OF OV-POSS NANOPARTICLES ON THE VULCANIZATION KINETICS OF NATURAL RUBBER COMPOUNDS

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dc.contributor.authorÜçtepe, E.
dc.contributor.authorYaz?c?, N.
dc.contributor.authorKodal, M.
dc.contributor.authorKaraa?aç, B.
dc.contributor.authorÖzkoç, G.
dc.date.accessioned2024-05-19T14:34:11Z
dc.date.available2024-05-19T14:34:11Z
dc.date.issued2021
dc.departmentİstinye Üniversitesien_US
dc.description.abstractPolyhedral oligomeric silsesquioxanes (POSSs) are new-generation additives, which can provide improved properties of polymer matrices due to physical and/or chemical interactions between the polymer molecules and their reactive sites. In the case ofrubber-based polymeric systems, POSSs are also able to accompany a vulcanization reaction. This study aimed to investigatethe effect of octavinyl functionalized POSS (OV-POSS) on the sulphur vulcanization of a model natural rubber (NR) based compound.The reaction kinetics was studied using various kinetic approaches based on moving die rheometry and differential scanningcalorimetry. Rheometric data was evaluated using a common non-linear cure kinetic model, called the Isayev and DengModel. The Kissinger, Flynn-Wall-Ozawa and Crane Models were used to evaluate the thermal data for curing reactions. All themodels were found to be able to analyze the vulcanization kinetics of OV-POSS containing NR-based rubber compounds as wellas the effect of the OV-POSS incorporation © 2021. Materiali in Tehnologije. All Rights Reserved.en_US
dc.description.sponsorship116M587; Türkiye Bilimsel ve Teknolojik Araştirma Kurumu, TÜBITAKen_US
dc.description.sponsorshipThis study was supported by The Scientific and Technological Research Council of Turkey (TUBITAK) (Project No: 116M587).en_US
dc.identifier.doi10.17222/MIT.2021.240
dc.identifier.endpage831en_US
dc.identifier.issn1580-2949
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85124256008en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage825en_US
dc.identifier.urihttps://doi.org/10.17222/MIT.2021.240
dc.identifier.urihttps://hdl.handle.net/20.500.12713/4429
dc.identifier.volume55en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherInstitute of Metals Technologyen_US
dc.relation.ispartofMateriali in Tehnologijeen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmz20240519_kaen_US
dc.subjectNatural Rubberen_US
dc.subjectPossen_US
dc.subjectRheologyen_US
dc.subjectVulcanization Kineticsen_US
dc.titleEFFECTS OF OV-POSS NANOPARTICLES ON THE VULCANIZATION KINETICS OF NATURAL RUBBER COMPOUNDSen_US
dc.typeArticleen_US

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