Discrete versus polymeric structures of coordination compounds of copper (II) with (pyridin-2-yl)methylenenicotinohydrazide and a library of dicarboxylic acids

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dc.authoridMonica Benito
dc.authoridGhodrat Mahmoudi / 0000-0002-4846-5283
dc.authoridElies Molins / 0000-0003-1012-0551
dc.authoridEnnio Zangrando
dc.authoridMasoumeh Servati Gargari / 0009-0009-4524-3333
dc.authoridAntonio Frontera / 0000-0001-7840-2139
dc.authoridDamir A. Safin
dc.authorwosidGhodrat Mahmoudi / AAB-6892-2022
dc.contributor.authorBenito, Monica
dc.contributor.authorMahmoudi, Ghodrat
dc.contributor.authorMolins, Elies
dc.contributor.authorZangrando, Ennio
dc.contributor.authorGargari, Masoumeh Servati
dc.contributor.authorFrontera, Antonio
dc.contributor.authorSafin, Damir A.
dc.date.accessioned2025-04-18T09:13:47Z
dc.date.available2025-04-18T09:13:47Z
dc.date.issued05.10.2024
dc.departmentİstinye Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümü
dc.description.abstractA series of copper(II) discrete and polymeric coordination compounds, namely [{CuL(H2O)}(2)(fum)] (1), [{CuL(H2O)}(2)(mes)] (2), [Cu2L2(glu)](n)2n(H2O) (32n(H2O)) and [Cu3L2(adi)(2)](n) (4) were fabricated from (pyridin-2-yl)methylenenicotinohydrazide (HL) and a library of dicarboxylic acids, namely fumaric acid (H(2)fum), mesaconic acid (H(2)mes), glutaric acid (H(2)glu) and adipic acid (H(2)adi), using evaporative crystallization, grinding and slurry synthesis methods. The obtained coordination compounds have been fully characterized by single crystal X-ray diffraction revealing different types of complexes depending on the linker length, viz. from dinuclear complexes for the shorter linkers (fumaric and mesaconic acids) to 1D and 2D coordination polymers for longer glutaric and adipic acids. Thermal stability and spectroscopic features (FTIR and diffuse reflectance) of complexes were also studied. For the nonpolymeric compounds 1 and 2, the supramolecular assemblies driven by a combination of antiparallel pi-stacking and hydrogen bonding interactions have been studied and compared using DFT calculations, MEP surface analysis and a combination of QTAIM and NCIplot computational tools.
dc.identifier.citationBenito, M., Mahmoudi, G., Molins, E., Zangrando, E., Gargari, M. S., Frontera, A., & Safin, D. A. (2024). Discrete versus polymeric structures of coordination compounds of copper (II) with (pyridin-2-yl) methylenenicotinohydrazide and a library of dicarboxylic acids. Inorganic Chemistry Communications, 170, 113150.
dc.identifier.doi10.1016/j.inoche.2024.113150
dc.identifier.issn1387-7003
dc.identifier.issue170
dc.identifier.scopus2-s2.0-85204470400
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://www.webofscience.com/wos/woscc/full-record/WOS:001321798200001
dc.identifier.urihttps://hdl.handle.net/20.500.12713/6725
dc.identifier.wosWOS:001321798200001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorMahmoudi, Ghodrat
dc.institutionauthoridGhodrat Mahmoudi / 0000-0002-4846-5283
dc.language.isoen
dc.publisherELSEVIER
dc.relation.ispartofInorganıc Chemıstry Communıcatıons
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectKeywords PlusHIRSHFELD SURFACE-ANALYSISMETAL-ORGANIC FRAMEWORKSCRYSTAL-STRUCTURESHYDROGEN-BONDCOMPLEXESNI(II)PI5-PHENYL-2
dc.subject2'-BIPYRIDINEMECHANOCHEMISTRYTHIOUREAS
dc.titleDiscrete versus polymeric structures of coordination compounds of copper (II) with (pyridin-2-yl)methylenenicotinohydrazide and a library of dicarboxylic acids
dc.typeArticle

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