Ultra-Facile fabrication of hydrogels through photopolymerization of oleyl methacrylate and epoxidized oleyl methacrylate with N-Isopropylacrylamide

Basit Öğe Kaydı
dc.authoridPınar Çakır Hatır / 0000-0002-3806-7118
dc.authorscopusidPınar Çakır Hatır / 57203277694
dc.authorwosidPınar Çakır Hatır / S-8707-2019
dc.contributor.authorHatır, Pınar Çakır
dc.contributor.authorÇaylı, Gökhan
dc.date.accessioned2022-06-09T13:40:49Z
dc.date.available2022-06-09T13:40:49Z
dc.date.issued2022en_US
dc.departmentİstinye Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Biyomedikal Mühendisliği Bölümüen_US
dc.description.abstractThis study reports an ultra-facile, economical, and environmentally friendly hydrogel synthesis method using renewable raw materials. The synthesis and photopolymerization of oleyl methacrylate (OM) and the epoxidized derivative of OM monomers are evaluated. In the first step, oleyl alcohol is esterified with methacryloyl chloride and then epoxidized via the Prilezhaev reaction. These monomers are used for hydrogel synthesis. For this purpose, they are polymerized with N-isopropyl acrylamide, N,N-methylene bis(acrylamide), or ethylene glycol dimethacrylate (EDGMA) via the photopolymerization technique. Novel hydrogels are successfully fabricated using a green process. Epoxidized OM-based hydrogel achieves an excellent yield of 87.1%. Moreover, low-energy UV irradiation and short reaction times reduces energy consumption. The thermal properties of the gels are also considered by differential scanning calorimetry (DSC) and thermogravimetric analysis techniques. DSC results reveal that the epoxidized OM-based hydrogel exhibits a melting peak at 84.5 degrees C. The highest 5% weight loss temperature is obtained for the OM-EDGMA copolymer as an indicator of thermal stability.en_US
dc.identifier.citationHatir, P. C., Cayli, G. (2022). Ultra-Facile fabrication of hydrogels through photopolymerization of oleyl methacrylate and epoxidized oleyl methacrylate with N-Isopropylacrylamide. Macromoleculer Chemistry and Physics.en_US
dc.identifier.doi10.1002/macp.202200002en_US
dc.identifier.issn1022-1352en_US
dc.identifier.scopus2-s2.0-85128746499en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/macp.202200002
dc.identifier.urihttps://hdl.handle.net/20.500.12713/2852
dc.identifier.wosWOS:000786981000001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorHatır, Pınar Çakır
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAGen_US
dc.relation.ispartofMACROMOLECULAR CHEMISTRY AND PHYSICSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectGreen Processesen_US
dc.subjectOleic Aciden_US
dc.subjectPlant-Oil Based Monomersen_US
dc.subjectRenewable Resourcesen_US
dc.subjectThermoresponsive Hydrogelsen_US
dc.titleUltra-Facile fabrication of hydrogels through photopolymerization of oleyl methacrylate and epoxidized oleyl methacrylate with N-Isopropylacrylamideen_US
dc.typeArticleen_US

Dosyalar

Lisans paketi
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Biyomedikal Mühendisliği Bölümü Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu