Novel and eco-friendly hydrophobic treatment of cotton and polyester fabrics based-on octavinyl and aminopropylisobutyl polyhedral oligomeric

Basit Öğe Kaydı
dc.contributor.authorAkbasak, Tughan
dc.contributor.authorKodal, Mehmet
dc.contributor.authorMert, Olcay
dc.contributor.authorOzkoc, Gueralp
dc.date.accessioned2024-05-19T14:46:15Z
dc.date.available2024-05-19T14:46:15Z
dc.date.issued2023
dc.departmentİstinye Üniversitesien_US
dc.description.abstractThe hydrophobicity of cotton and polyester fabrics plays a significant role in various industrial applications. Anchoring hydrophobic chemicals onto the fabric surface is one of the major strategies. Fluorinated chemicals are widely employed to construct hydrophobic surfaces. However, alternative hydrophobic coatings are urgently sought by researchers due to the potential risks and hazards of fluorinated chemicals. Polyhedral oligomeric silsesquioxanes (POSS) are one of the most potential alternatives as they increase the roughness and lower the surface energy through chemical enhancement of the surface. In this work, hydrophobic cotton and polyester surfaces were fabricated anchoring Octavinyl POSS (OL-POSS) and Aminopropylisobutyl POSS (AM-POSS) onto the surface via one-step dip-coating technique. To enhance the surface roughness and the hydrophobicity, Ul-traviolet (UV) radiation was employed with Benzoyl Peroxide (BPO) initiator. Water contact angle (WCA) of both fabrics increased from 0 degrees to 136 degrees using 5% POSS coatings with initiator and UV present. Water absorption duration (WAD) also increased from several seconds up to 310 min. Furthermore, 5% POSS modified fabrics gave similar or better WAD values when compared to coatings treated with fluorinated chemicals. The findings confirmed that OL-POSS and AM-POSS coatings are eligible environmentally friendly candidates for the replacement of fluorinated chemicals.en_US
dc.description.sponsorshipAkkim Kimya Sanayi ve Ticaret A.S., Yalova, Turkeyen_US
dc.description.sponsorshipThis work was financially supported by Akkim Kimya Sanayi ve Ticaret A.S., Yalova, Turkey, and the authors would like to thank Mrs. Burgin Yalgin Helvaci for her assistance with ATR-FTIR and WCA analyses, Mr. Hasan Kayali for his assistance with coating experiments, Dr. Mehmet Onur Arcan for the reaction mechanism drawing and Mr. Semih Sahan for his analytical support.en_US
dc.identifier.doi10.1016/j.polymer.2023.125723
dc.identifier.issn0032-3861
dc.identifier.issn1873-2291
dc.identifier.scopus2-s2.0-85146705443en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org10.1016/j.polymer.2023.125723
dc.identifier.urihttps://hdl.handle.net/20.500.12713/5478
dc.identifier.volume268en_US
dc.identifier.wosWOS:000963338500001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofPolymeren_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240519_kaen_US
dc.subjectPolyhedral Oligomeric Silsesquioxanes (Poss)en_US
dc.subjectOctavinyl Possen_US
dc.subjectAminopropylisobutyl Possen_US
dc.subjectHydrophobic Cotton Fabricsen_US
dc.subjectHydrophobic Polyester Fabricsen_US
dc.subjectDipping Methoden_US
dc.titleNovel and eco-friendly hydrophobic treatment of cotton and polyester fabrics based-on octavinyl and aminopropylisobutyl polyhedral oligomericen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu