Hydrolytic stability of hydroxyphenyl boronic Acids(HPBAs) and employment of Poly(HPBAs) for voltammetric determination of fluoride levels in dental formulations and beverages; Significance of raw DPV Data for chemometric discrimination
Yükleniyor...
Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
John Wiley and Sons Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Physicochemical and electrochemical properties of hydroxyphenyl boronic acids(HPBAs) and their use in fluoride determinations were investigated. HPBAs were electropolymerized at pH 1.0–11.0 in 40–60 %(v/v) methanol-buffer. Differential pulse voltammetry(DPV) determinations of fluoride (with 1.0×10?5–1.0×10?4 M linearity based on potential shift) using poly(HPBAs) glassy carbon electrodes(GCEs) have ?45.49 to +34.40 % error range. Significance of raw DPV data for chemometric discrimination was investigated by principle component analysis. This is the first demonstration of fluoride determination with poly(HPBAs)GCEs and chemometric discrimination of pharmaceutical formulations so far. Due to the lack of experimental data in literature, current findings will make a contribution to literature. © 2022 Wiley-VCH GmbH.
Açıklama
Anahtar Kelimeler
Boroxines, Chemoinformatics, DPV, Hydroxyphenyl Boronic Acids, TGA
Kaynak
Electroanalysis
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
Sayı
Künye
Gulay Der, F., Yalcin, G., Ozcan Bulbul, E., Ileri, H., Cihan, B., Gokcan, M., . . . Kilinc, E. (2022). Hydrolytic stability of hydroxyphenyl boronic acids(HPBAs) and employment of poly(HPBAs) for voltammetric determination of fluoride levels in dental formulations and beverages; significance of raw DPV data for chemometric discrimination. Electroanalysis, doi:10.1002/elan.202200012
