Versatile copper(ii) discrete and polymeric coordination compounds with (pyridine-2-yl)methylenenicotinohydrazide and azelaic acid

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dc.authorscopusidGhodrat Mahmoudi / 15765751200
dc.authorwosidGhodrat Mahmoudi / AAB-6892-2022
dc.contributor.authorBenito, Mónica
dc.contributor.authorMahmoudi, Ghodrat
dc.contributor.authorMolins, Elies
dc.contributor.authorZangrando, Ennio
dc.contributor.authorServati Gargari, Masoumeh
dc.contributor.authorGomila, Rosa M.
dc.contributor.authorFrontera, Antonio
dc.contributor.authorSafin, Damir A.
dc.date.accessioned2025-04-17T06:41:56Z
dc.date.available2025-04-17T06:41:56Z
dc.date.issued2024
dc.departmentİstinye Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümü
dc.description.abstractIn this contribution, a series of copper(ii) discrete and polymeric coordination compounds, namely [Cu3L2(aze)2]nnH2O (1nH2O), [CuL2]H2O (2H2O) and [CuL(H2O)(Haze)]H2O (3H2O) were fabricated from (pyridin-2-yl)methylenenicotinohydrazide (HL) and azelaic acid (H2aze), using evaporative crystallization, grinding and slurry synthesis methods. The solvent crystallization method produced a crystalline precipitate of complex 1nH2O. The filtrate allowed the production of crystals of complex 3H2O. The grinding synthetic method gave rise to a mixture of complexes 1nH2O, 2H2O and an undetermined phase. Results of the slurry synthetic approach highly depend on the stirring time. The obtained coordination compounds have been fully characterized by single crystal X-ray diffraction revealing different structures of complexes, viz. from mononuclear homo- and heteroleptic complexes (2 and 3) to a 1D heteroleptic coordination polymer (1). DFT calculations on non-polymeric complexes were conducted to evaluate the hydrogen-bonding and pi-stacking interactions that play a critical role in the solid-state structures of complexes 2 and 3. Additionally, the impact of co-crystallized water molecules, which enhance the pi-stacking interactions, was analyzed using energy decomposition analysis.
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidades European Regional Development Fund
dc.identifier.citationBenito, M., Mahmoudi, G., Molins, E., Zangrando, E., Gargari, M. S., Gomila, R. M., ... & Safin, D. A. (2025). Versatile copper (ii) discrete and polymeric coordination compounds with (pyridine-2-yl) methylenenicotinohydrazide and azelaic acid. CrystEngComm, 27(2), 164-175.
dc.identifier.doi10.1039/d4ce01021c
dc.identifier.endpage175
dc.identifier.issn1466-8033
dc.identifier.issue2
dc.identifier.scopus2-s2.0-85211336138
dc.identifier.scopusqualityQ2
dc.identifier.startpage164
dc.identifier.urihttp://dx.doi.org/10.1039/d4ce01021c
dc.identifier.urihttps://hdl.handle.net/20.500.12713/6099
dc.identifier.volume27
dc.identifier.wosWOS:001369618300001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorMahmoudi, Ghodrat
dc.institutionauthoridGhodrat Mahmoudi / 0000-0002-4846-5283
dc.language.isoen
dc.publisherRoyal society of chemistry
dc.relation.ispartofCrystEngComm
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleVersatile copper(ii) discrete and polymeric coordination compounds with (pyridine-2-yl)methylenenicotinohydrazide and azelaic acid
dc.typeArticle

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