Synthesis and Characterization of New-Type Soluble ?-Substituted Zinc Phthalocyanine Derivative of Clofoctol

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dc.authoridPaolesse, Roberto/0000-0002-2380-1404
dc.authoridMagna, Gabriele/0000-0003-2140-0110
dc.authorwosidPaolesse, Roberto/B-8966-2013
dc.authorwosidDi Natale, Corrado/M-8701-2014
dc.authorwosidMagna, Gabriele/IUP-3252-2023
dc.contributor.authorDridi, Sabrine
dc.contributor.authorKhiari, Jamel Eddine
dc.contributor.authorMagna, Gabriele
dc.contributor.authorStefanelli, Manuela
dc.contributor.authorLvova, Larisa
dc.contributor.authorMandoj, Federica
dc.contributor.authorKhezami, Khaoula
dc.date.accessioned2024-05-19T14:46:13Z
dc.date.available2024-05-19T14:46:13Z
dc.date.issued2023
dc.departmentİstinye Üniversitesien_US
dc.description.abstractIn this work, we have described the synthesis and characterization of novel zinc (II) phthalocyanine bearing four 2-(2,4-dichloro-benzyl)-4-(1,1,3,3-tetramethyl-butyl)-phenoxy substituents on the peripheral positions. The compound was characterized by elemental analysis and different spectroscopic techniques, such as FT-IR, H-1 NMR, MALDI-TOF, and UV-Vis. The Zn (II) phthalocyanine shows excellent solubility in organic solvents such as dichloromethane (DCM), n-hexane, chloroform, tetrahydrofuran (THF), and toluene. Photochemical and electrochemical characterizations of the complex were performed by UV-Vis, fluorescence spectroscopy, and cyclic voltammetry. Its good solubility allows a direct deposition of this compound as film, which has been tested as a solid-state sensing material in gravimetric chemical sensors for gas detection, and the obtained results indicate its potential for qualitative discrimination and quantitative assessment of various volatile organic compounds, among them methanol, n-hexane, triethylamine (TEA), toluene and DCM, in a wide concentration range.en_US
dc.description.sponsorshipMinistry of Higher Education and Scientific Research-Tunisiaen_US
dc.description.sponsorshipThis research was funded by the Ministry of Higher Education and Scientific Research-Tunisia.en_US
dc.identifier.doi10.3390/molecules28104102
dc.identifier.issn1420-3049
dc.identifier.issue10en_US
dc.identifier.pmid37241842en_US
dc.identifier.scopus2-s2.0-85160379137en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org10.3390/molecules28104102
dc.identifier.urihttps://hdl.handle.net/20.500.12713/5470
dc.identifier.volume28en_US
dc.identifier.wosWOS:000996976300001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherMdpien_US
dc.relation.ispartofMoleculesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmz20240519_kaen_US
dc.subjectPhthalocyaninesen_US
dc.subjectSolubilityen_US
dc.subjectGas Sensorsen_US
dc.subjectQuartz Microbalancesen_US
dc.titleSynthesis and Characterization of New-Type Soluble ?-Substituted Zinc Phthalocyanine Derivative of Clofoctolen_US
dc.typeArticleen_US

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