Synthesis, characterization and VOCs adsorption kinetics of diethylstilbestrol-substituted metallophthalocyanines

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dc.authoridÖzer Bekaroğlu / 0000-0002-9249-2385en_US
dc.authorwosidÖzer Bekaroğlu / N-9731-2013
dc.contributor.authorKaki, Esra
dc.contributor.authorGöğsu, Nurcan
dc.contributor.authorAltındal, Ahmet
dc.contributor.authorSalih, Bekir
dc.contributor.authorBekaroğlu, Özer
dc.date.accessioned2021-08-07T07:17:34Z
dc.date.available2021-08-07T07:17:34Z
dc.date.issued2020en_US
dc.departmentİstinye Üniversitesi, Eczacılık Fakültesi, Eczacılık Temel Bilimleri Bölümüen_US
dc.description.abstractCompound (4, 4'-hex-3-ene-3, 4-diyl)bis(4, 1-phenylene)bis(oxy)diphthalonitrile 3 was synthesized by the reaction of 4-nitrophthalonitrile 1 and diethylstilbestrol 2 in dry DMF in presence of dry K2CO3. New mononuclear phthalocyanines 4-6 were obtained from compound 3 by addition of the corresponding metal salts [Co(OAc)2. 4H2O, Zn(OAc)2. 2H2O and Cu(OAc)2]. The novel compounds were characterized by elemental analysis and FT-IR, UV-vis, 1H-NMR and MALDI-TOF mass spectroscopy techniques. The effects of four main groups of organic vapors on these novel compounds were studied and discussed. The adsorption kinetics of alkanes (n-hexane and n-octane), alcohols (methanol and 2-proponal), chlorinated hydrocarbons (dichloromethane and trichloromethane) and amines (diethylamine and triethylamine) on 4-6 were examined using three adsorption kinetic models: the Elovich equation, the pseudo-first-order equations and Ritchie’s equation. Results show that the linear regression analysis with respect to the pseudo-second-order rate equations generates a straight line that best fits the data of adsorption of alcohols and chlorinated hydrocarbons on Pc films. On the other hand, the Elovich equation generates a straight line that best fits the data of adsorption of alkanes and amines.en_US
dc.identifier.citationKakı, E., Gögsu, N., Altındal, A., Salih, B., & Bekaroǧlu, Ö. (2020). Synthesis, characterization and VOCs adsorption kinetics of diethylstilbestrol-substituted metallophthalocyanines. In PORPHYRIN SCIENCE BY WOMEN: In 3 Volumes (pp. 991-999).en_US
dc.identifier.doi10.1142/S1088424619500196en_US
dc.identifier.endpage999en_US
dc.identifier.isbn978-981122355-6
dc.identifier.scopus2-s2.0-85109781408en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage991en_US
dc.identifier.urihttps://doi.org/10.1142/S1088424619500196
dc.identifier.urihttps://hdl.handle.net/20.500.12713/1977
dc.identifier.wosWOS:000460467300018en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorBekaroğlu, Özer
dc.language.isoenen_US
dc.publisherWorld Scientific Publishing Co.en_US
dc.relation.ispartofPorphyrin Science By Women (In 3 Volumes)en_US
dc.relation.publicationcategoryKitap Bölümü - Uluslararasıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAdsorption Kineticsen_US
dc.subjectAlkanesen_US
dc.subjectAminesen_US
dc.subjectMononuclearen_US
dc.subjectPhthalocyanineen_US
dc.titleSynthesis, characterization and VOCs adsorption kinetics of diethylstilbestrol-substituted metallophthalocyaninesen_US
dc.typeBook Chapteren_US

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