Synthesis, characterization and VOCs adsorption kinetics of diethylstilbestrol-substituted metallophthalocyanines

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dc.authoridÖzer Bekaroğlu / 0000-0002-9249-2385en_US
dc.authorwosidÖzer Bekaroğlu / N-9731-2013
dc.contributor.authorKaki, Esra
dc.contributor.authorGogsu, Nurcan
dc.contributor.authorAltindal, Ahmet
dc.contributor.authorSalih, Bekir
dc.contributor.authorBekaroğlu, Özer
dc.date.accessioned2020-08-30T20:07:09Z
dc.date.available2020-08-30T20:07:09Z
dc.date.issued2019
dc.departmentİstinye Üniversitesi, Eczacılık Fakültesi, Eczacılık Temel Bilimleri Bölümüen_US
dc.descriptionBekaroglu, Ozer ---/0000-0002-9249-2385en_US
dc.descriptionWOS: 000460467300018en_US
dc.description.abstractCompound (4,4'-hex-3-ene-3,4-diyl)bis(4,1-phenylene)bis(oxy)diphthalonitrile 3 was synthesized by the reaction of 4-nitrophthalonitrile 1 and diethylstilbestrol 2 in dry DMF in presence of dry K2CO3 . New mononuclear phthalocyanines 4-6 were obtained from compound 3 by addition of the corresponding metal salts [Co(OAc)(2)center dot 4H(2)O, Zn(OAc)(2)center dot 2H(2)O and Cu(OAc)(2)]. The novel compounds were characterized by elemental analysis and FT-IR, UV-vis, H-1-NMR and MALDI-TOF mass spectroscopy techniques. The effects of four main groups of organic vapors on these novel compounds were studied and discussed. The adsorption kinetics of alkanes (n-hexane and n-octane), alcohols (methanol and 2-proponal), chlorinated hydrocarbons (dichlommethane and trichloromethane) and amines (diethylamine and triethylamine) on 4-6 were examined using three adsorption kinetic models: the Elovich equation, the pseudo-first-order equations and Ritchie's equation. Results show that the linear regression analysis with respect to the pseudo-second-order rate equations generates a straight line that best fits the data of adsorption of alcohols and chlorinated hydrocarbons on Pc films. On the other hand, the Elovich equation generates a straight line that best fits the data of adsorption of alkanes and amines.en_US
dc.description.sponsorshipTurkish Academy of Sciences TUBATurkish Academy of Sciences; Turkish Marmara University; Commission of Scientific Research Projects [Science-C-YLP-121114-0360]; Yildiz Technical University Commission of Scientific Research ProjectsYildiz Technical University [2014-01-01-YL01, 2014-01-01-KAP01]en_US
dc.description.sponsorshipWe thank the Turkish Academy of Sciences TUBA and Marmara University and the Commission of Scientific Research Projects (Project No: Science-C-YLP-121114-0360) for their support. This study was also supported by the Yildiz Technical University Commission of Scientific Research Projects under Grant No. 2014-01-01-YL01 and 2014-01-01-KAP01.en_US
dc.identifier.citationKaki, E., Gogsu, N., Altindal, A., Salih, B., & Bekaroglu, O. (2019). Synthesis, characterization and VOCs adsorption kinetics of diethylstilbestrol-substituted metallophthalocyanines. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 23(1–2), 166–174. https://doi.org/10.1142/S1088424619500196en_US
dc.identifier.doi10.1142/S1088424619500196en_US
dc.identifier.endpage174en_US
dc.identifier.issn1088-4246en_US
dc.identifier.issn1099-1409en_US
dc.identifier.scopus2-s2.0-85109781408en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage166en_US
dc.identifier.urihttps://doi.org/10.1142/S1088424619500196
dc.identifier.urihttps://hdl.handle.net/20.500.12713/704
dc.identifier.volume23en_US
dc.identifier.wosWOS:000460467300018en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorBekaroğlu, Özeren_US
dc.language.isoenen_US
dc.publisherWorld Sci Publ Co Incen_US
dc.relation.ispartofJournal of Porphyrins and Phthalocyaninesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalocyanineen_US
dc.subjectMononuclearen_US
dc.subjectAdsorption Kineticsen_US
dc.subjectAminesen_US
dc.subjectAlkanesen_US
dc.titleSynthesis, characterization and VOCs adsorption kinetics of diethylstilbestrol-substituted metallophthalocyaninesen_US
dc.typeArticleen_US

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