Soybean oil based allyl acrylates and methacrylates: synthesis, characterization, and polymerization
Yükleniyor...
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
WILEY-V C H VERLAG GMBH
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, a simple synthesis method for the allylic acrylates and methacrylates of soybean oil is evaluated. As a model compound, allylic acrylation and methacrylation of methyl oleate is also studied. IR and H-1 NMR techniques are used in order to characterize all the allylic esters. Although homopolymerization of allylic esters is unsuccessful, copolymers of the allylic esters with acrylic acid, methacrylic acid, n butyl acrylate, and styrene are obtained as low load bearing solids. Copolymerization products of acrylated soybean oil (ACSO) and methacrylted soybean oil (METACSO with styrene show rubbery properties. METACSO-Styrene and ACSO-styrene copolymers exhibit 35.3 and 24.9 kPa tensile strengths with more than 200% of elongation. Thermal stabilities of the synthesized polymers are measured by TGA technique. The copolymers of methyl oleate-based allyl acrylates and methacrylates exhibit higher 5% weight loss temperature than the copolymers of allylic acrylate and methacrylate of soybean oil.
Açıklama
Anahtar Kelimeler
Allyl Acrylates, Allylic Bromides, Plant Oil Triglycerides, Renewable Resources, Soybean Oil
Kaynak
MACROMOLECULAR CHEMISTRY AND PHYSICS
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
Sayı
Künye
Çaylı, G., & Hatır, P. Ç. (2022). Soybean Oil Based Allyl Acrylates and Methacrylates: Synthesis, Characterization and Polymerization. Macromolecular Chemistry and Physics, 2100460.
