Soybean oil based allyl acrylates and methacrylates: synthesis, characterization, and polymerization

Basit Öğe Kaydı
dc.authoridPınar Çakır Hatır / 0000-0002-3806-7118en_US
dc.authorscopusidPınar Çakır Hatır / 57203277694
dc.authorwosidPınar Çakır Hatır / S-8707-2019en_US
dc.contributor.authorÇaylı, Gökhan
dc.contributor.authorHatır, Pınar Çakır
dc.date.accessioned2022-11-11T07:46:45Z
dc.date.available2022-11-11T07:46:45Z
dc.date.issued2022en_US
dc.departmentİstinye Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Biyomedikal Mühendisliği Bölümüen_US
dc.description.abstractIn this study, a simple synthesis method for the allylic acrylates and methacrylates of soybean oil is evaluated. As a model compound, allylic acrylation and methacrylation of methyl oleate is also studied. IR and H-1 NMR techniques are used in order to characterize all the allylic esters. Although homopolymerization of allylic esters is unsuccessful, copolymers of the allylic esters with acrylic acid, methacrylic acid, n butyl acrylate, and styrene are obtained as low load bearing solids. Copolymerization products of acrylated soybean oil (ACSO) and methacrylted soybean oil (METACSO with styrene show rubbery properties. METACSO-Styrene and ACSO-styrene copolymers exhibit 35.3 and 24.9 kPa tensile strengths with more than 200% of elongation. Thermal stabilities of the synthesized polymers are measured by TGA technique. The copolymers of methyl oleate-based allyl acrylates and methacrylates exhibit higher 5% weight loss temperature than the copolymers of allylic acrylate and methacrylate of soybean oil.en_US
dc.identifier.citationÇaylı, G., & Hatır, P. Ç. (2022). Soybean Oil Based Allyl Acrylates and Methacrylates: Synthesis, Characterization and Polymerization. Macromolecular Chemistry and Physics, 2100460.en_US
dc.identifier.doi10.1002/macp.202100460en_US
dc.identifier.issn1022-1352en_US
dc.identifier.scopus2-s2.0-85140134655en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttp://dx.doi.org/10.1002/macp.202100460
dc.identifier.uri1521-3935
dc.identifier.urihttps://hdl.handle.net/20.500.12713/3313
dc.identifier.wosWOS:000870552600001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorHatır, Pınar Çakır
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofMACROMOLECULAR CHEMISTRY AND PHYSICSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAllyl Acrylatesen_US
dc.subjectAllylic Bromidesen_US
dc.subjectPlant Oil Triglyceridesen_US
dc.subjectRenewable Resourcesen_US
dc.subjectSoybean Oilen_US
dc.titleSoybean oil based allyl acrylates and methacrylates: synthesis, characterization, and polymerizationen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
Macro Chemistry Physics - 2022 - ayli - Soybean Oil Based Allyl Acrylates and Methacrylates Synthesis Characterization .pdf
Boyut:
913.93 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Biyomedikal Mühendisliği Bölümü Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu