Metal-support interaction in pt nanodisk-carbon nitride catalyst: insight from theory and experiment

Küçük Resim Yok

Tarih

2024

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

MDPI

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

Metal-support interaction plays a critical role in determining the eventual catalytic activity of metals loaded on supporting substrates. This interaction can sometimes cause a significant drop in the metallic property of the loaded metal and, hence, a drop in catalytic activity in the reactions, especially in those for which low charge carrier transfer resistance is a necessary parameter. Therefore, there should be a case-by-case experimental or theoretical (or both) in-depth investigation to understand the role of support on each metal. Here, onto a layered porous carbon nitride (g-CN), we grew single crystalline Pt nanodisks (Pt@g-CN) with a lateral average size of 21 nm, followed by various characterisations such as electron microscopy techniques, and the measurement of electrocatalytic activity in the O-2 reduction reaction (ORR). We found that intercalating Pt nanodisks in the g-CN interlayers causes an increase in electrocatalytic activity. We investigated the bonding mechanism between carbon support and platinum using density functional theory and applied the d-band theory to understand the catalytic performance. Analysis of Pt's density of states and electronic population across layers sheds light on the catalytic behaviour of Pt nanoparticles, particularly in relation to their thickness and proximity to the g-CN support interface. Our simulation reveals an optimum thickness of similar to 11 angstrom, under which the catalytic performance deteriorates.

Açıklama

Anahtar Kelimeler

Metal-Support Interaction, Hard Template, Crystalline Pt, Oxygen Reduction Reaction (ORR), Porous Layered Nitride, Density Functional Theory, D-Band Theory

Kaynak

Nanomaterials

WoS Q Değeri

Q2

Scopus Q Değeri

Q1

Cilt

14

Sayı

11

Künye

Doustkhah, E., Kotb, A., Balkan, T., & Assadi, M. H. N. (2024). Metal–Support Interaction in Pt Nanodisk–Carbon Nitride Catalyst: Insight from Theory and Experiment. Nanomaterials, 14(11), 921.