An accurate and sensitive determination of selected pesticides in mixed fruit juice samples using the combination of a simple and efficient microextraction method and GC-MS with a matrix matching calibration strategy

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dc.authoridBodur, Süleyman/0000-0002-2994-9047
dc.authorwosidBodur, Süleyman/AHB-4581-2022
dc.contributor.authorBodur, Sueleyman
dc.contributor.authorTutar, Bahar Karademir
dc.contributor.authorTutar, Omer Faruk
dc.contributor.authorBakirdere, Sezgin
dc.date.accessioned2024-05-19T14:50:36Z
dc.date.available2024-05-19T14:50:36Z
dc.date.issued2024
dc.departmentİstinye Üniversitesien_US
dc.description.abstractPesticides have been used on several fruits, vegetables and cereals to control harmful organisms in order to increase the quality of products; however, these substances cause serious health effects. Therefore, an accurate and sensitive analytical method should be developed for the determination of pesticides to evaluate their toxicity. In this study, an efficient microextraction strategy was applied to preconcentrate eight different selected pesticides from mixed fruit juice samples prior to gas chromatography-mass spectrometry detection. All significant parameters such as spraying number, extraction solvent type, sample volume and mixing type/period belonging to the developed extraction method were elaborately optimized to get low detection limits. After the optimization studies, system analytical performance studies were carried out and limit of detection (LOD) values varied from 0.04 mu g /kg-1 to 1.99 mu g kg-1 (mass based) for the selected analytes. Under the optimum experimental conditions, spiking recovery experiments were performed in the mixed fruit juice samples to evaluate the applicability and accuracy of the proposed method. The recovery results were recorded in the range of 81.4-123.5% with acceptable standard deviations by applying a matrix matching calibration strategy. The proposed analytical method can be used for the qualitative and quantitative determination of selected pesticides in the mixed fruit juice samples and can also be applied to other fruit juice samples using a matrix matching calibration strategy. A simple and efficient microextraction method was proposed to preconcentrate eight different pesticides from mixed fruit juice samples prior to GC-MS measurement.en_US
dc.identifier.doi10.1039/d3ay02327c
dc.identifier.endpage1370en_US
dc.identifier.issn1759-9660
dc.identifier.issn1759-9679
dc.identifier.issue9en_US
dc.identifier.pmid38345087en_US
dc.identifier.scopus2-s2.0-85185160504en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1363en_US
dc.identifier.urihttps://doi.org10.1039/d3ay02327c
dc.identifier.urihttps://hdl.handle.net/20.500.12713/5757
dc.identifier.volume16en_US
dc.identifier.wosWOS:001160033800001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofAnalytical Methodsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240519_kaen_US
dc.subjectLiquid-Liquid Microextractionen_US
dc.subjectLeavesen_US
dc.titleAn accurate and sensitive determination of selected pesticides in mixed fruit juice samples using the combination of a simple and efficient microextraction method and GC-MS with a matrix matching calibration strategyen_US
dc.typeArticleen_US

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