Crystal structure of bis(mesityl)(pyrrol-1-yl)borane
Yükleniyor...
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Int Union Crystallography
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In the crystal structure of the title compound, C22H26BN, the B atom acts to reduce the delocalization of the nitrogen lone-pair electron density into the pyrrole ring, so that the two N-C bonds increase in length to 1.4005 (14) and 1.3981 (14) A degrees. The N-B bond length is 1.4425 (15) A degrees, which is longer than a typical N-B bond because the nitrogen lone pair is not fully available to participate in the bond.
Açıklama
Anahtar Kelimeler
Crystal Structure, Pyrroloborane, N-B Bonding, Pi Delocalization
Kaynak
Acta Crystallographica Section E-Crystallographic Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Cilt
79
Sayı
1
Künye
Sahin, O., & Wallis, J. D. (2023). Crystal structure of bis (mesityl)(pyrrol-1-yl) borane. Acta Crystallographica Section E: Crystallographic Communications, 79(1), 50-53.
